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On the left side of the equation experimental results are reduced to one number which by the expression on the right side is interpreted in terms of the order parameters and the orientation of the related transition moment On first glance it seems that S and D can be evaluated from the bands due to any two transitions of different, but well known orientations within a rigid molecule However, this is possible only with quite limited accuracy due to the anisotropy of the internal field This field originates from the dipole moments being induced in the individual molecules by the external radiation field Its anisotropy is a consequence of the molecular alignment and impedes the comparison of different bands Several approaches how to evaluate and to eliminate the influence were proposed (Neugebauer, 1954; Vuks, 1966; Haller et al.

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, 1973; de Jeu and Bordewijk, I978), however at least for the infrared range convincing results for practical applications have not been reported yet The influence could be minimized by evaluating the dichroic ratios related to two spectrally neighboured bands the transition moments of which are parallel to one of the molecular transverse axes each: Due to the uniaxiality of the phase these bands should be similarly influenced, so that reliable information on D results (Korte, 1983; Lampen, 1991) To be sure about the transition moments being strictly parallel to one of the three molecular axes, the symmetry of the molecules should be C ,, or D2h (Michl and Thulstrup, 1986), what in strict sense is hardly found with mesogenic molecules On the other hand, just the fact that a dichroism band is negative - leading to R < 1 and a negative value on the left side of Eq.

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Maintenance association End Point In a CFM-enabled network, MEPs can be any SAP or SDP binding in a service and associated to a MA. A set of MEPs configured with the same MA ID defines an MA. CFM tests detect connectivity failures between any pair of local and remote MEPs in a MA.

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46-3 - indicates that the transition moment forms a large angle with the molecular long axis A positive dichroism band is related with a transition moment which primarily projects on the long axis Already such qualitative hints can be helpful when molecular vibrations are to be assigned More often than for mesogenic molecules, such assignments are useful with respect to the great number of molecules which do not form a liquid crystalline phase on their own Such assignments can be obtained equivalently when the molecules are dissolved in a nematic liquid crystal (Belkhakem and Jordanov, 1990, 1991a, 1991b, 1992; with respect to chiral molecules see Kuball et al, 1979) The attainable concentration is limited, since the non-mesogenic molecules disturb the mesomorphic order and reduce the temperature range of its existence primarily by lowering the clearing temperature.

steam export. A concept with a higher degree of heat integration is described in Ref. [34]. The concept has been derived from the FLOX burner (FLOX = flameless oxidation in the gas phase) [35]. This combustion regime can be attained with highly preheated fresh air in combination with intensive recirculation in the combustion chamber, and features extremely low emissions. Fresh air preheating is accomplished in the FLOX burner through countercurrent heat exchange with the hot flue gases in an

The solute molecules experience an equivalent cage as the mesogenic molecules do and are aligned therein according to their anisotropy As for all studies of diluted solutions, the bands of the solvent might obscure the relevant bands of the solute Fortunately enough the choice of nematics is nowadays quite wide and some types such as bi-cyclohexyl.

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Value: String Gettable: Yes Settable: No Description: The GUID of the object from the directory store.

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