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The actual strength of the analytical signal can be characterized by the equivalent thickness d,; this is the sample thickness necessary to produce an equally pronounced transmission spectrum (Hamck, 1967). In the calculation for the ATR case, the increased field strength at the interface in the rarer medium along with its exponential decay are taken into account. The increase of field strength is different for the s-polarized and p-polarized components and thus, their effective thicknesses differ. The p-polarized component is always related to a larger equivalent thickness and thus to a more pronounced absorption signal. As the penetration depth, also the effective thicknesses are proportional to the wavelength, so that bands are relatively more pronounced at low wavenumbers. For large angles of incidence, the penetration depth is greater than the effective thickness, so that transmission through a +thick layer would yield a more pronounced spectrum than ATR does (see Fig. 6.4-15). Close to the critical angle d, exceeds dp: the increase of the field strength at the interface makes ATR more sensitive than a transmission measurement would be. However ATR is often applied to make very thin layers effective, e.g. when dealing with aqueous solutions. The effective thickness varies strongly upon approaching the critical angle, so that the dispersion of the refractive index through an absorption band causes considerable effect on the spectra: bands appear to be distorted particularly by tailing at their longer-wavelength sides and maxima are shifted rendering questionable traditional evaluation schemes. Remedial measures are increasing the angle of reflection or choosing a denser medium of higher refractive index. Alternatively the experiment could be complemented to yield birt ean 128 Bar code EAN - 128 Font in BIRT Reports — OpenText - Forums
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